Its Lewis structure is shown below: There are 4 electron domains around the central atom P (3 single bonds and 1 double bond). Step 8 in determining the Lewis Structure of PO4(3-) PO 4 3-Step 8 Picture so Far: (Numbers next to atoms are their formal charges) Starting at the upper right corner and moving clockwise we can make 4 resonance structures that expand the P octet to 10. ReO 3 – Rhenium trioxide; CaTiO 3 – Perovskite; MgAl 2 O 4 – Spinel; Mg 2 TiO 4 – Inverse Spinel; Simple Solids. YCl 3 – Yttrium trichloride; BiI 3 – Bismuth triiodide; Li 3 Bi - Lithium Bismuthide; Advanced solid structures. AB3 structures. There are four bonding pairs between P and the four oxygen atoms and no lone pairs on P. Therefore, the electron pair geometry is tetrahedral and the molecular geometry is tetrahedral. This gives an electron geometry or parent geometry of tetrahedral. Phosphate ion == The Lewis structure of PO4^3- must accommodate 32 valence electrons.
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